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91.
McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L-1) and high SO inf4 sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO inf4 sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical  相似文献   
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Menhaden are one of the most abundant components of fish communities in Gulf and Atlantic estuaries. Juvenile menhaden have been reported to have zooplankton, phytoplankton, andSpartina-derived detritus in their guts. However, there has been disagreement over the importance of the detritus as a food source. We show, using physiological and stable isotope evidence, that detritus can be used by juvenile Gulf menhaden. Their diet is very roughly 30% detritus- and 70% plankton-based.  相似文献   
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Flow-through seagrass core microcosms were used to examine responses of species and processes to a logarithmic gradient of dosing with14C-labeled tributyltin-chloride (TBT-CI). Experiments involved delivery of TBT-CI to the water column of replicate cores of a treatment (n=16) once per week; one-half of the cores were sacrificed after 3 wk of dosing, the others were dosed for 6 wk. Initial water column concentrations for the three treatments averaged 0.205, 2.23, and 22.21 μg I?1, expressed as the TBT+ cation, but these concentrations dropped rapidly. Retained14C tracer, an estimate of total organotin species, was distributed to sediments, plants, and other biological tissues, all of whose tracer concentrations increased with time. Measures to indicate responses of both autotrophic and heterotrophic organisms were made; in general, treatment effects were demonstrable statistically only at the highest dose level. Accumulation of chlorophyll and biomass on glass slides was highest when suspended for the entire experiment in the water of the highest treatment; this unexpected result was perhaps an indirect effect related to reduced grazing activity in the microcosms. The highest dose of TBT-CI resulted in virtual population mortality of a few macrobenthic species and decreased loss of plant material in litter bags, both demonstrated within the first 3 wk of dosing. Reduced litter loss was coincident with mortality of an amphipod (Cymadusa compta) capable of shredding plant material, and a causal relation between the two effects is plausible. Thus, if concentrated to similar levels in aThalassia bed, TBT+ may have direct species-level effects and process-level effects, potentially causing ecosystem change via disruption of a species-process linkage influential in seagrass detrital food web dynamics.  相似文献   
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Following the 2010–2011 earthquakes in Christchurch, New Zealand, many nonprofit organizations changed or expanded services to address emergent or compounded risks. This research is based on interviews with thirty local community nonprofit managers and discussions with five staff focus groups conducted in 2014. Preexisting nonprofits with flexible organizational structures and emergent nonprofits succeeded in providing services during the emergency response and early recovery phases; nonprofits contracted with the government were better suited for long-term recovery. Shared resources among nonprofit agency connections contributed to successful transitions from response to recovery. Similar organizational resilience factors might occur in other major cities following disasters.  相似文献   
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Consolidated to friable carbonate rocks found in the Lee Stocking Island area in the Exuma Cays include: (1) reef rock, (2) channel stromatolites, (3) shallow-water hardgrounds, (4) beachrock rimming the islands and (5) Pleistocene bedrock.

The most common cement fabrics observed are: aragonitic fibers, which include acicular fan-druse and square-tipped coarse fibers cementing beachrock and stromatolites; and an isopachous needle-fiber rim cementing hardgrounds and stromatolites.

Less common are high-Mg calcite bladed textures of the reef rock and stromatolites. Two types of blades are present: the more common stubby variety of either high-Mg or low-Mg calcite, and an elongated variety of high-Mg calcite which was found in only three beachrock samples.

Aragonitic micrite envelopes usually surround grains in beachrock, hardgrounds and stromatolites, but only in association with fibrous cement. An aragonitic crust cements the surfaces of lime mud beds of the tidal channel, while a high-Mg calcite cryptocrystalline cement occurs in all the rock types. Calcified algal filaments of high-Mg calcite, from the abundant green and blue-green algae in the area, are a primary cement in stromatolites and a secondary cement in hardgrounds and beachrock. A low-Mg calcite equant spar cements the Pleistocene samples and is associated with meteoric diagenesis and cementation of the Pleistocene surface.

Cement precipitation coincides with the path of the cool oceanic water from Exuma Sound as it warms and loses CO2 and moves up onto the bank near Lee Stocking with the incoming tide. Cryptocrystalline cement is the first and commonest cement forming to the seaward while platformward, fibrous cements become predominant. As suggested by their crystal size and location on the shelf margin, we think that the reef rock cryptocrystalline material are the fastest forming of the cements, where the incoming oceanic water is more saturated with respect to calcium carbonate and undergoes the most significant warming. The rate of the warming and degassing process is thought to increase in the tidal channel though the cementation rate is thought to fall slightly in response to a reduced availability of calcium carbonate. On the platform interior further warming and degassing are believed to cause cement precipitation and the development of hardgrounds, but these may form at a slower rate than that of the margin, though this rate is still quite high. Cementation gradients occur from the tidal channel to the intertidal zones of: (1) west Norman's Pond Cay, where cement fabric suggests a reduced calcium carbonate availability, and (2) west Lee Stocking Island, where a change in mineralogy suggests a change in water chemistry.

Thus, a sequence of cement fabrics and mineralogies can be traced. Micritic textures occur in a more seaward position; fine, fibrous aragonite fibers in a more lagoonal and levee position; and coarser aragonite fibers and Mg-calcite cements in the intertidal and supratidal position. This sequence is thought to track the evolution of the water mass.  相似文献   

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